Periodic Classification of Elements
Periodic Classification of the Elements
Classification:
Grouping of elements into
different classes is called periodic classification of elements. Elements are
arranged into groups (columns) and periods (Rows )based on their properties. This method is requires arranging the
elements that are alike and separating the elements that are unlike.
Need of Classification :
It helps us understand how different elements
form different compounds. The number of elements discovered has
increased, making it difficult to remember the behavior and properties of these
elements. Hence it is important to classify elements according to
their properties.
Dobereiner’s law Triads:
Johann Wolfgang Dobereiner, a German chemist, classified the known elements in
groups of three elements on the basis of similarities in their properties.
These groups were called triads.
According to this law,
when elements are arranged in order of increasing atomic masses, groups of
three elements, having similar properties are obtained. The atomic mass of
middle element of the triad is nearly equal to the average of the atomic masses of
the other two elements.
For Example Li (6.9), Na (23), K (39).
Characteristics of Triads:
1. Properties of elements in
each triad were similar.
2. Atomic mass of the middle
element was roughly the average of the atomic masses of the other two elements.
Limitations:
Dobereiner could
identify only three triads. He was not able to prepare triads of all the known
elements.
Newlands’ Law of Octaves:
John Newlands’, an
English scientist, arranged the known elements in the order of increasing
atomic masses. He found that the physical and chemical properties of every
first element is very similar to that every eighth element. He compared this to the octaves found in
music. Therefore, he called it is the ‘ Law of Octaves’. It is known as ‘
Newlands' law of octaves ’ .
Characteristics
of Newlands’ Law of Octaves:
·
It contained the elements from hydrogen to thorium.
·
Properties of every eighth element were similar to that of
the first element.
Limitations of
Newlands’ law of Octaves:
1. The law was applicable to
elements up to calcium (Ca).
2. In order to fit elements
into the table, Newlands’ adjusted two elements like cobalt and nickel in the same
slot.
3. At the time of Newlands'
only 56 elements were known in nature and Newlands' assume that no more
elements will be discovered the future But, later on , several new elements
were discovered, whose properties did not fit into the law of octaves.
4. Newlands' law of Octaves
worked well with lighter elements only.
Mendeleev’s Periodic Table:
D. I. Mendeleev, a
Russian chemist, was the most important contributor to the early development of
a periodic table of elements wherein the elements were arranged on the basis of
their atomic mass and chemical properties.
Mendeleev use the following
criteria to formulate his periodic law.
1. All the elements were
arranged on the basis of their atomic masses.
2. He reacted all then known
elements with hydrogen (to form hydrides) and oxygen (to form oxides)
On the bases of the above
two criteria he formulated the law called as the Mendeleev’s law of the periodic
table:
“The properties of the elements are periodic
functions of their atomic masses.”
Characteristics of Mendeleev’s Periodic Table:
1. Mendeleev arranged all the
63 known elements in increasing order of their atomic masses.
2. The table contained
vertical columns called ‘groups’ and horizontal rows called ‘periods’.
3. The elements with similar
physical and chemical properties came under the same groups.
4. Mendeleev’s stated that the
properties of elements are the periodic function of their atomic masses.
Achievements of Mendeleev’s Periodic Table:
1. Through this table, it was
very easy to study the physical and chemical properties of various elements.
2. Mendeleev left some gaps
in his periodic table.
He predicted the existence of some elements that had not been discovered at
that time. Later on elements like scandium, gallium and germanium were discovered
to fill these gaps.
3. The Nobel gases like
helium, neon and argon, which were discovered later, were placed in a new group
without disturbing the existing order.
Limitations of Mendeleev’s Periodic Table :
1. No fixed positions were
given to hydrogen in the Mendeleev’s periodic table.
2. Positions of Isotopes of
all elements was not certain according to Mendeleev’s periodic table.
3. Atomic masses did not
increase in a regular manner in going from one element to the next.
4. Anomalous pairs of
elements: Cobalt (Co) has higher atomic weights but was placed before
Nickel (Ni) in the periodic table.
5. He could not explain the
cause of periodicity among the elements
Modem Periodic Table:
Henry Moseley, gave a new
property of elements, ‘atomic number’
and this was I adopted as the basis of Modem Periodic Table.
Modern Periodic table.
1. Elements are arranged in
increasing order in their atomic numbers.
2. These are 7 period and 18
groups.
3. Insert gases are placed in
a separate group i.e. 18 group.
4. All the transitional
elements are placed in 3 to 12 groups.
5. Metal and non metals are
widely separated from one another.
6. Hydrogen is given a
special position in modern Periodic table
Modem Periodic Law:
“Properties of elements
are a periodic function of their atomic numbers”.
Characteristics of the modern periodic table
or
Long form of periodic table
1. The modem periodic table
consists of 18 groups and 7 periods.
2. Elements present in any
one group have the same number of valence electrons.
3. The number of shells
increases as we go down the group.
4. Elements present in any
one period, contain the same number of shells.
5. Each period marks a new
electronic shell getting filled.
Trends in the Modern Periodic Table:
Valency:
Valency of an element is
determined by the number of valence electrons present in the outermost shell of
its atom. In simple terms the combining
capacity of the atom is called as valancy.
Group: Valency of
elements in a particular group is same.
Period: Valency of
elements in a period first increases from one to four and then decreases to
zero.
Atomic Size:
Atomic size refers to the
radius of an atom. It is the distance from the center of the nucleus to the outermost
electron present in the atom.
Group: In a group, atomic
size and radii increases from top to bottom.
Period: In a period,
atomic size and radii decreases from left to right.
Metallic and Non-metallic Properties:
The tendency to lose
electrons from the outermost shell of an atom, is called metallic character of
an element.
The tendency to gain
electrons from the outermost shell of an atom, is called non-metallic character
of an element.
Note:
Groups in Modern Periodic
Table
The modern periodic table
contains 18 vertical columns known as groups.
Group 1 elements are
known as alkali metals.
Group 2 elements are known as alkaline earth metals.
Group 15 elements are known as pnicogens.
Group 16 elements are known as chalcogens.
Group 17 elements are known as halogens.
Group 18 elements are known as noble gases.
Non- metallic character:-
The tendency to gain electrons from the outermost shell of an atom is called non-metallic
character of an element.
Ionization energy:-
It is defined as the
energy required to remove an electron completely from an isolated gaseous atom
of an element. The energy required to remove the first electron is called first
ionization energy.
Variation in a group:-
Ionisation energy goes on decreasing down a group.
Variation in a period:-
It goes on increasing generally along a period from left to right.
Page no. 112
Q.1. Yes,
Dobereiner’s triads also exist in the
column of Newland’s octaves.
E.G.; Li(Lithium),
Na(Sodium), K(Potassium) is a triad of Dobereiner also exist in the coloumn of
Newland’s octaves.
Q.2. See back.
Page no. 116
Q.1. Elements Oxides
1. K (Potassium) K20
2. C (Carbon) C02
3. Al (Aluminium) Al203
4. Si (Silicon) Si02
5. Ba (Barium) Ba0
Q.2. (i) Scandium (EKKA-
boron): Sc
(ii) Germanium (EKKA- silicon): Ge
Q.3. Mendeleev use the
following criteria for his periodic table:
(i) Mendeleev arranged the elements on the
basis of their fundamental property i.e., the atomic mass.
(ii) Mendeleev concentrated on the compound formed
by elements with oxygen(oxides) and hydrogen (hydrides). He selected hydrogen
and oxygen as they are very reactive and formed compounds with most elements.
Q.4. Noble gases are very
less reactive element. These gases were discovered very late, because they are very
inert and placing them in a separate group, does not disturb the existing order
put forward by Mendeleev.
Page no. 120
Q.1. Modern periodic
table removes various anomalies of Mendeleev’s periodic table.
Achievements of modern periodic
table:- See back
Q.2. The two
elements that show the chemical
reactions similar to magnesium are:-
(i) Beryllium
(ii) Calcium
Q.3. (i)
(i) Sodium
(ii) Hydrogen
(iii)Lithium
(ii)
Beryllium
Magnesium
Calcium
Helium
Neon
Argon
Q.4. (i) Lithium(Li),
Sodium(Na), Potassium(K) atoms belong to same group and have same numbers of
electrons in their outermost shells.
(ii) Helium(He) and Neon
(Ne) both belong to last group and have their outermost shell filled.
Q.5. Among the first ten
elements only Lithium and Beryllium are metals.
Q.6. Be and Ga are excepted to be most metallic out of be
and Ga . Ga is bigger in size and hence has greater tendency to lose electrons
than Be. Therefore, Ga is more metallic than Be.
Excerise 121
Q.2. ‘X’ is a metal
element and is in the same group as (B) Mg(Magnesium) metal.
Q.3.( a) Neon (2,8)
(b) Magnesium(2+8+2=12)
(c) Silicon (2,8,4)
(d) Boron(2,3)
(e) Carbon(2,4)
Q.4. (a) All elements of
this column have 3 electrons in their valence shell like Boron.
(b) All elements of this
column have 7 electrons in their valence shell like fluorine.
Q.5. (A) its atomic
number is 17(equal) to total number of electrons i.e. (2+8+7=17)
(B) Electron configuration
of these elements are:-
N=2,5 F= 2,7 P= 2,8,5 AR= 2,8,8
These properties of this
element are similar to F (Fluorine) element as both have same number of valence
electrons (electrons is the outermost shell)
Q.6. ‘A’ is an non metal
because group 17 contain non metal.
(b) ‘c’ is less reactive
than ‘A’ as non metallic properties decreases on moving down in a group.
(c) ‘c’ will smaller in
size than ‘B’ as atomic size decreases as we move from left to right in a
period.
(d) Anion will be formed
by A because non metal form anions only.
Q.7. The electronic
configuration of nitrogen and phosphorus
Elements
Nitrogen
Phosphorus
Atomic No.
7
15
Electronic configuration
2,5
2,8,5
Nitrogen will be more electro-negative
because due to increases in size the electro negativity of non metals goes on
decreasing on moving down the group
Q.8. We can determine the
position of any element in the modern periodic table be its electronic
configuration on number of electrons in the outermost shell shows the group
number and total number of shell of an atom shows the period to which it
belongs.
E.g. Atomic number of
solution=11
Electronic
Configuration=2,8,1
It contains 1 electron in
outermost shell. So it belongs to group 1 and total number of shell are 3 So,
it belong to 3rd period.
Q.9
The electronic configuration of all the elements are given below.
Atomicno.
1 20
21
38
Electronic
confuration
2,8,2
2,8,8,1
2,8,8,1
2,8,8,3
2,8,8,8,2
So the elements having
atomic number 12 and 38 resemble with the properties of calcium as both the
elements have some number of valence electrons as calcium.
Q10.
Mendeleev periodic table
1. Elements are arranged in
increasing order of their atomic masses.
2. These are 6 period and 8
groups.
3. Inert gases were not known
at the time of Mendeleev.
4. All the transitional
elements are placed in 8 groups.
5. Many metals and non metals
are group together.
6. No fixed position was
given to hydrogen in Mendeleev periodic table.